Tautomería y reactividad de 2-alquiltioisomünchnonas

  1. Díaz Álvarez, Jesús
Dirigida por:
  1. Reyes Babiano Caballero Director/a
  2. Ignacio López-Coca Martín Director/a

Universidad de defensa: Universidad de Extremadura

Fecha de defensa: 06 de febrero de 2006

Tribunal:
  1. José Fuentes Mota Presidente/a
  2. M. Goodman Jonathan Secretario/a
  3. Pedro Cintas Moreno Vocal
  4. Fernando Pedro Cossío Mora Vocal
  5. Jose Albertino Almeida Figueiredo Vocal

Tipo: Tesis

Resumen

Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*) calculations.