Tautomería y reactividad de 2-alquiltioisomünchnonas

  1. Díaz Álvarez, Jesús
Supervised by:
  1. Reyes Babiano Caballero Director
  2. Ignacio López-Coca Martín Director

Defence university: Universidad de Extremadura

Fecha de defensa: 06 February 2006

Committee:
  1. José Fuentes Mota Chair
  2. M. Goodman Jonathan Secretary
  3. Pedro Cintas Moreno Committee member
  4. Fernando Pedro Cossío Mora Committee member
  5. Jose Albertino Almeida Figueiredo Committee member

Type: Thesis

Abstract

Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*) calculations.