Miguel Ángel
Huertos Mansilla
Publicaciones (46) Publicaciones de Miguel Ángel Huertos Mansilla
2024
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Direct chemoselective reduction of plant oils using silane catalysed by Rh(iii) complexes at ambient temperature
RSC Sustainability, Vol. 2, Núm. 4, pp. 1052-1057
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Inverse Isotope Effect for Aldehyde Hydrosilylation Catalyzed by a Hydrido-Silyl-Iridium(III) Complex
Organometallics
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Mild and Selective Hydrogenation of Unsaturated Compounds Using Mn/Water as a Hydrogen Gas Source
Organic Letters, Vol. 26, Núm. 11, pp. 2147-2151
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Unsaturated chiral-only-at-metal rhodium(iii) complexes bearing SiN-type ligands
Chemical Communications, Vol. 60, Núm. 80, pp. 11299-11302
2023
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Air-Stable 14-Electron Rhodium(III) Complexes Bearing Si,N Ligands as Catalysts in Hydrolysis of Silanes
Organometallics, Vol. 42, Núm. 20, pp. 2991-2998
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Catalytic activation of remote alkenes through silyl-rhodium(iii) complexes
Dalton Transactions, Vol. 52, Núm. 26, pp. 9090-9096
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Hydrogen Tunneling in Stoichiometric and Catalytic Reactions involving Transition Metals
ChemCatChem, Vol. 15, Núm. 24
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Tailor-Made Synthesis of Hydrosilanols, Hydrosiloxanes, and Silanediols Catalyzed by di-Silyl Rhodium(III) and Iridium(III) Complexes
Inorganic Chemistry, Vol. 62, Núm. 7, pp. 3095-3105
2022
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Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes
Angewandte Chemie - International Edition, Vol. 61, Núm. 36
2021
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Experimental and DFT studies on Hexacoordinated acyl(alkyl)and Pentacooordinated Hydroxyalkyl(phosphinite)erhodium(III). Catalytic Hydrolysis of Ammonia Borane
European Journal of Inorganic Chemistry, Vol. 2021, Núm. 9, pp. 879-891
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Oxidative Addition of Secondary Phosphine Oxides through Rh(I) Center: Hydrido-Phosphinito-Rh(III) Complexes and their Catalytic Activity in Hydrophosphinylation of Alkynes
European Journal of Inorganic Chemistry, Vol. 2021, Núm. 47, pp. 4935-4945
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Steric Effects in the Catalytic Tandem Isomerization-Hydrosilylation Reaction
ChemCatChem, Vol. 13, Núm. 5, pp. 1403-1409
2020
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Si-C(sp3) bond activation through oxidative addition at a Rh(i) centre
Dalton Transactions, Vol. 49, Núm. 17, pp. 5416-5419
2019
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(Diphenylphosphino)alkylaldehyde affords hydride- or alkyl-[(diphenylphosphino)alkylacyl]rhodium(iii) or (diphenylphosphino)alkylester complexes: Theoretical and experimental diastereoselectivity
Dalton Transactions, Vol. 48, Núm. 10, pp. 3300-3313
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A phosphine-stabilized silylene rhodium complex
Dalton Transactions, Vol. 48, Núm. 46, pp. 17179-17183
2018
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Alkene-alkyl interconversion: An experimental and computational study of the olefin insertion and β-hydride elimination processes
Dalton Transactions, Vol. 47, Núm. 19, pp. 6808-6818
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From Remote Alkenes to Linear Silanes or Allylsilanes depending on the Metal Center
ChemCatChem, Vol. 10, Núm. 10, pp. 2210-2213
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Ion-macromolecule interactions studied with model polyurethanes
Journal of Colloid and Interface Science, Vol. 509, pp. 102-112
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Rh(iii)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes
Dalton Transactions, Vol. 47, Núm. 45, pp. 16225-16231
2017
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Rhodium(III) Catalyzed Solvent-Free Tandem Isomerization–Hydrosilylation From Internal Alkenes to Linear Silanes
ChemCatChem, Vol. 9, Núm. 11, pp. 1901-1905