Polymer-based electrolytes for all-solid-state lithium-sulfur batteries
- JUDEZ LOPEZ, XABIER
- Lide Mercedes Rodríguez Martinez Director
- José Antonio González Marcos Director
Defence university: Universidad del País Vasco - Euskal Herriko Unibertsitatea
Fecha de defensa: 04 December 2019
- Juan Ramón González Velasco Chair
- Beatriz De Rivas Martín Secretary
- Frederic Aguesse Committee member
- L. J. Alemany Committee member
- Susanne Doerfler Committee member
Type: Thesis
Abstract
The development of more efficient and competitive batteries is crucial for a complete transition to more sustainable energy models. In this regard, all-solid-state lithium-sulfur batteries, especially those based on lightweight solid-polymer-electrolytes, present several benefits in comparison with conventional lithium-ion batteries. However, the performance of these batteries is not satisfactory yet due to challenges related to lithium/polymer compatibility. This work aims to understand the failure mechanism behind that poor performance, and propose different strategies to overcome those limitations. Those strategies include the use of electrolyte additives, electrolyte fillers, alternative imide salts, and fluorine-free salts.