Tautomería y reactividad de 2-alquiltioisomünchnonas
- Díaz Álvarez, Jesús
- Reyes Babiano Caballero Director
- Ignacio López-Coca Martín Director
Universidade de defensa: Universidad de Extremadura
Fecha de defensa: 06 de febreiro de 2006
- José Fuentes Mota Presidente/a
- M. Goodman Jonathan Secretario/a
- Pedro Cintas Moreno Vogal
- Fernando Pedro Cossío Mora Vogal
- Jose Albertino Almeida Figueiredo Vogal
Tipo: Tese
Resumo
Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*) calculations.