Tautomería y reactividad de 2-alquiltioisomünchnonas

  1. Díaz Álvarez, Jesús
unter der Leitung von:
  1. Reyes Babiano Caballero Doktorvater/Doktormutter
  2. Ignacio López-Coca Martín Doktorvater/Doktormutter

Universität der Verteidigung: Universidad de Extremadura

Fecha de defensa: 06 von Februar von 2006

Gericht:
  1. José Fuentes Mota Präsident/in
  2. M. Goodman Jonathan Sekretär/in
  3. Pedro Cintas Moreno Vocal
  4. Fernando Pedro Cossío Mora Vocal
  5. Jose Albertino Almeida Figueiredo Vocal

Art: Dissertation

Zusammenfassung

Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*) calculations.