Tautomería y reactividad de 2-alquiltioisomünchnonas
- Díaz Álvarez, Jesús
- Reyes Babiano Caballero Director/a
- Ignacio López-Coca Martín Director/a
Universitat de defensa: Universidad de Extremadura
Fecha de defensa: 06 de de febrer de 2006
- José Fuentes Mota President/a
- M. Goodman Jonathan Secretari/ària
- Pedro Cintas Moreno Vocal
- Fernando Pedro Cossío Mora Vocal
- Jose Albertino Almeida Figueiredo Vocal
Tipus: Tesi
Resum
Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*) calculations.