Tautomería y reactividad de 2-alquiltioisomünchnonas

  1. Díaz Álvarez, Jesús
Dirigida per:
  1. Reyes Babiano Caballero Director/a
  2. Ignacio López-Coca Martín Director/a

Universitat de defensa: Universidad de Extremadura

Fecha de defensa: 06 de de febrer de 2006

Tribunal:
  1. José Fuentes Mota President/a
  2. M. Goodman Jonathan Secretari/ària
  3. Pedro Cintas Moreno Vocal
  4. Fernando Pedro Cossío Mora Vocal
  5. Jose Albertino Almeida Figueiredo Vocal

Tipus: Tesi

Resum

Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*) calculations.